초록 |
In the present study, the crossover lattice equation of state was employed to calculate the solubulities of solids in supercritical solvents over a wide range of pressure and temperatures. The characteristic parameters of the pure components, appearing in the original sanchez-lacombe equation of state, were estimated using a molecular dynamic procudure (MD). The theoretically calculated solubilities were found to be in excellent agreement with the corresponding experimentally measured values, demonstrating the capability of the xLF EOS to predict the solubility of solids in supercritical solvents. |