학회 |
한국고분자학회 |
학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
권호 |
32권 2호 |
발표분야 |
분자전자 소재 및 소자 기술(분자전자 부문위원회) |
제목 |
Conducting Polymer Nano-structures self-assembled in Magnetic Ionic Liquids as a Template |
초록 |
We discovered a new polymerization method to fabricate nano-structured conducting polymers. The synthesis can be accomplished by just adding monomer to a magnetic ionic liquid bmim[FeCl4]. By simply adding monomer into bmim[FeCl4], a magnetic ionic liquid solvent, various nano-structures, such as nano-particles, nano-rods, and nano-tubes, of conductive polymer form immediately. Bmim[FeCl4] seems to play multiple roles in this reaction. The shape of polypyrrole nano-particles was synthesized and their size ranged around 60 nm. The conductivity of pelletized particles was 101-2 S/cm. Especially, from the N-methyl pyrrole monomer, more attractive nano-structured polymers were obtained as the tube form. The discovered polymerization process will provide the simplest and most costless method to fabricate various nano-sized conducting polymer materials. |
저자 |
김진열1, 김재택1, 송은아1, 민영근2, Hiro-o Hamaguchi2
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소속 |
1국민대, 2The Univ. of Tokyo |
키워드 |
Conducting Polymer; Nano-structures; Polypyrrole; Magnetic ionic liquids
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E-Mail |
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