화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.2225
발표분야 촉매 및 반응공학
제목 Highly active cathode of SOEC with double perovskite for high temperature H2O/CO2 co-electrolysis
초록 Recently, solid oxide electrolysis cell (SOEC) has become an attractive research field for reduction and utilization of carbon dioxide through converting electrical energy into chemical energy with high energy efficiency. However, conventional Ni based cathode used in the SOEC applications suffers from the redox instability and performance degradation. Here, we investigate double perovskite catalyst materials as a promising alternative cathode of SOEC for H2O/CO2 co-electrolysis. The double perovskite cathode cell exhibits outstanding performance at a cell voltage of 1.3 V with a current density value of 0.570 A/cm2 at 800 ℃ for the co-electrolysis operation. Moreover, performance degradation under electrolysis operation at a constant applied current was not observed for 50 h with double perovskite cathode. Thereby, by virtue of these properties, double perovskite materials developed here can be applied as promising ceramic catalyst materials for the SOEC cathode.
저자 박성민1, 노유성1, 김윤곤2, 한현수1, 김원배1
소속 1포항공대 화학공학과, 2광주과학기술원 신소재공학부
키워드 촉매 및 반응공학
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