| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자와 연료전지 |
| 제목 |
A Study on Characteristics and Performance of Membrane-Electrode Assemblies Employing Chloromethylated Polysulfone-Based Solid Alkaline Electrolytes |
| 초록 |
Solid alkaline fuel cells(SAFCs) are a new type of fuel cells with the configuration of polymer electrolyte membrane fuel cells(PEMFCs), but the principle of alkaline fuel cells(AFCs). In other words, polymeric anion-exchange membranes(AEMs) as an electrolyte enable to combine both advantages of PEMFCs and AFCs. They are easy to assemble all the components, able to use non-precious catalyst and possible to provide a favorable oxygen reduction reaction. For the aforementioned advantages, development of AEMs with good OH- conductivity is prerequisite. In this study, chloromethlyated polysulfone-based AEMs aminated by mono- and/or diamine were employed in membrane-electrolyte assemblies(MEAs). The catalyst slurries were prepared by mixing the catalyst powder(i.e., Ni/C, Pt/C and Ag/C), deionized water and the lab.-made ionomer binder to the polymeric electrolyte (5%) in DMF or DMAc. Fabricated MEAs were characterized and evaluated at H2/air, 50~100% RH, 40~80 oC and ambient pressure. |
| 저자 |
박진수, 박석희, 박구곤, 임성대, 양태현, 김창수, 이원용
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| 소속 |
한국에너지기술(연) |
| 키워드 |
Solid alkaline fuel cell; Polymeric electrolyte; Membrane-electrode assembly; Non-precious catalyst
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| E-Mail |
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