| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Cross-linked sulfonated poly(arylene ether sulfone) membrane using bishydroxy perfluoropolyether as a cross-linker for high-performance proton exchange membrane fuel cell |
| 초록 |
The high performance cross-linked sulfonated poly(arylene ether sulfone) membrane (C-SPAES) is prepared by simple and effective cross-linking method using bishydroxy perfluoropolyether (PFPE) as a cross-linker for fuel cell application. The C-SPAES shows much improved chemical and mechanical properties due to the cross-linked structure and reasonably high proton conductivity compared to the linear SPAES due to the effective phase-separated morphology between hydrocarbon parts from SPAES and perfluorinated moieties from PFPE. Under, 90 oC and 50% RH conditions, the C-SPAES exhibits an outstanding cell performance (1.17 W cm-2 at 0.65 V) ascribed to its well-developed phase-separated morphology and enhanced interfacial compatibility between electrode and membrane. Furthermore, C-SPAES reveals notable durability during the cell operation. |
| 저자 |
한주성1, 이종찬1, 김기현2, 김정환1, 이현희1
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| 소속 |
1서울대, 2경상대 |
| 키워드 |
proton exchange membrane; bishydroxy perfluoropolyether; cross-linking; sulfonated poly(arylene ether sulfone); phase separation
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| E-Mail |
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