| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Synthesis and Properties of Poly(3-ethynyl-N-pentylpyridinium iodide) |
| 초록 |
The ionic polyacetylenes have potentials as materials for mixed ionic and electronic conductivity, energy storage devices such as batteries, permselective membrane, light-emitting devices. Here, an ionic polyacetylene, poly(3-ethynyl-N-pentylpyridinium iodide), was synthesized by the non-catalyst polymerization of 3-ethynylpyridine using 1-iodopentane. The kinetics of the polymer redox process was found to be mainly controlled by the reactant diffusion process from the experiment of the oxidation current density of polymer versus the scan rate. The photoluminescence maximum peak of polymer was located at 534 nm, which corresponds to the photon energy of 2.32 eV. |
| 저자 |
조민진1, 제갈영순2, 심상연3, 박영일4, 진성호5, 박종욱1
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| 소속 |
1가톨릭대, 2경일대, 3강릉원주대, 4한국화학(연), 5부산대 |
| 키워드 |
Polyacetylene; 3-ethynylpyridine; non-catalyst; characterization; photoluminescence
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| E-Mail |
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