화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터)
권호 20권 1호, p.93
발표분야 공업화학
제목 Direct Spraying Approach for Synthesis  of ZIF-7 Membranes by Electrospray deposition
초록 ZIFs are promising materials for advanced membrane applications due to their desirable properties, which enable them to recognize specific target molecules based on molecular sieving mechanism and/or adsorption affinity. However, their large scale commercial applications still remain challenge because of the absence of a synthesis method that offers reproducibility, scalability, and cost-effectiveness. To this end, here we report our work of synthesizing supported zeolitic imidazolate framework ZIF-7 films and membranes in a facile and time-efficient manner at ambient pressure using a simple electrospray deposition technique. The membranes obtained under optimized conditions outperformed previously reported ZIF-7 membranes for H2/CO2 separation while showing rather noticeable improvement in H2 permeance which is roughly 4 to 10 times higher than the previous counterparts.
저자 김진수, Victor Manuel Aceituno Melgar, 고영채, 이정희
소속 경희대
키워드 zeolitic imidazolate frameworks; membrane; ZIF-7
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