학회 |
한국화학공학회 |
학술대회 |
2014년 봄 (04/23 ~ 04/25, 창원컨벤션센터) |
권호 |
20권 1호, p.93 |
발표분야 |
공업화학 |
제목 |
Direct Spraying Approach for Synthesis of ZIF-7 Membranes by Electrospray deposition |
초록 |
ZIFs are promising materials for advanced membrane applications due to their desirable properties, which enable them to recognize specific target molecules based on molecular sieving mechanism and/or adsorption affinity. However, their large scale commercial applications still remain challenge because of the absence of a synthesis method that offers reproducibility, scalability, and cost-effectiveness. To this end, here we report our work of synthesizing supported zeolitic imidazolate framework ZIF-7 films and membranes in a facile and time-efficient manner at ambient pressure using a simple electrospray deposition technique. The membranes obtained under optimized conditions outperformed previously reported ZIF-7 membranes for H2/CO2 separation while showing rather noticeable improvement in H2 permeance which is roughly 4 to 10 times higher than the previous counterparts. |
저자 |
김진수, Victor Manuel Aceituno Melgar, 고영채, 이정희
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소속 |
경희대 |
키워드 |
zeolitic imidazolate frameworks; membrane; ZIF-7
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E-Mail |
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원문파일 |
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