화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 가을 (11/02 ~ 11/04, 경원대학교)
권호 15권 2호
발표분야 고분자
제목 The synthesis of primary hydroxyl terminated polyepichlorohydrin in 10L mini pilot scale
초록 Epichlorohydrin was polymerized using boron trifluoride etherate as catalyst in presence of diol in 10L mini pilot scale. The prepolymer was modificated by end capping material before the termination reaction of polymerization. The synthesized of polymer were characterized by derivatizing them using trifluoroacetic anhydride and analyzing the resulting ester by 1H-NMR. The molecular weight and structural charaterization of prepolymer was investigated by GPC and FT-IR.
저자 김두기1, 김정수1, 김호림2, 안용환2, 노시태1
소속 1한양대, 2한화 여수사업장
키워드 cationic polymerization; polyepichlorohydrin; end capping
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