화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 가을 (10/13 ~ 10/14, 제주 ICC)
권호 30권 2호
발표분야 기능성 고분자
제목 Preparation and Characterization of Carbon Aerogels by Sol-Gel Polycondensation
초록 In this work, the carbon aerogels with high BET surface area were prepared by sol–gel polycondensation of resorcinol and furfural in isopropanol using hexamethylenetetramine (HMTA) as a catalyst, and then directly drying the organic gels under isopropanol freeze-drying conditions, followed by carbonization under a nitrogen atmosphere. The preparation conditions of carbon aerogels were explored by changing the mole ratio of resorcinol to basic catalyst HMTA (R/C) and the mole ratio of resorcinol to furfural (R/F). The effect of these prepared conditions on the porous structure of the carbon aerogels was studied by nitrogen adsorption isotherms. The characteristics of carbon aerogels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Accessibility of pores and aerogel performance as electrodes in electric-double layer capacitor (EDLCs) was also electrochemically investigated.
저자 서민강, 박수진
소속 한국화학(연)
키워드 carbon aerogels; sol-gel polycondensation; resorcinol-furfural; hexamethylenetetramine; electric-double layer capacitor
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