화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 가을 (10/13 ~ 10/14, 제주 ICC)
권호 30권 2호
발표분야 분자전자 부문위원회
제목 Effects of Thermal Annealing on Bulk-Heterojunction Photovoltaic Devices with Perylenebis(dicarboximide) Derivatives as Electron Acceptors.
초록 Current progress on organic photovoltaic devices from the standpoint of increasing power conversion efficiency (PCE) is mainly attributed to the bulk heterojunction structure. Further increase of the PCE is required for commercial applications of organic photovoltaic solar cells. The search of new materials with good performance characteristics as well as the improvement in the device fabrication has been a subject of importance. Perylene diimide derivatives (PDIs) are good candidates as electron accepting and transporting materials for bulk-heterojunction photovoltaic device, because PDIs have large molar absorption coefficients, good electron accepting properties and possible generation of highly conducting direction along the π- π stacking axis.
We will compare the optical and thermal properties of no functional group substituted swallow tailed PDI (PDI-C9) and pyrrolidyl group substituted one (5-PDI). And the effects of thermal annealing on the photovoltaic properties with PDIs as electron acceptors and P3HT as an electron donor will be presented.
저자 신원석1, 정환희2, 김미경2, 진성호3, 김미라1, 이진국2, 이재욱4, 제갈영순5
소속 1플라스틱정보소재연구센터, 2부산대, 3플라스틱정보소재연구센터 / 부산대, 4동아대, 5경일대
키워드 perylene diimide; photovoltaic device; thermal stability; thermal annealing
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