| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
chemical fixation of CO2 into polycarbonates by zinc glutarate and its derivatives |
| 초록 |
A heterogeneous zinc glutarate (ZnGA) catalyst and its derivatives were prepared from various zinc and glutarate sources. The ZnGA single crystals (sc-ZnGA), with a monoclinic lattice unit cell, as determined by X-ray single-crystal structural analysis. The structural details of the ZnGA catalyst are crucial in helping to elucidate its activity in the copolymerization reactions between carbon dioxide (CO2) and alkylene oxides. The activity of the ZnGA catalyst in the copolymerization of CO2 and PO was found to depend on the zinc source used, and its ability to produce a catalyst of large surface area and high crystallinity (≥77%). Modification of the glutarate ligand with electron-donating or withdrawing substituents failed to enhance the ZnGA catalyst activity further, indicating that glutarate is the best ligand for the Zn metal ion to achieve a high catalytic activity in the CO2 copolymerization with PO. |
| 저자 |
최준만1, 박삼대2, 김진철2, 김동민2, 정정운2, 노예철2, 안병철2, 권원상2, 김경태2, 김미희2, 고용기2, 정성민2, 이문호2
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| 소속 |
1포항공과대, 2포항공대화학과 |
| 키워드 |
CO2 |
| E-Mail |
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