| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Kinetic study on reversible addition-fragmentation chain transfer (RAFT) process for copolymerization of three methacrylate monomers |
| 초록 |
Reversible addition-fragmentation transfer (RAFT) polymerization, one of well-known living polymerizations, yields a product with designed molecular weight, low molecular weight distribution, and well defined structure. Kinetic study on RAFT process of copolymerization system is important because the ratio of monomers in a polymer chain affects the property of the polymer, and every chain in RAFT polymerization system grows simultaneously. In this study, ArF photoresist composed of three different methacrylate monomers with different functions was synthesized via RAFT polymerization using 2-cyanopropyl dithionaphthalate (CPDN) as a chain transfer agent (CTA). The conversion of each monomer was measured by 1H-NMR, and molecular weight and PDI of polymer were checked by GPC. The effects of several factors including the initial ratio of monomers and the ratio of CTA to monomers or initiator on kinetics of monomers were checked. |
| 저자 |
손해성1, 차상호1, 이원기1, 이종찬1, 김명선2, 윤효진2, 백세경2, 김수경2, 함지윤2, 김영호2, 채승기2, 이준경3, 이재우3, 김재현3
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| 소속 |
1서울대, 2(주) 삼성전자, 3(주) 동진 쎄미켐 |
| 키워드 |
ArF; photoresist; RAFT
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| E-Mail |
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