| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
대학원생 구두발표 |
| 제목 |
Characterization of amphiphilic diblock copolythiophene in thin film |
| 초록 |
We charaterized a diblock copolymer, poly(3-hexylthiophene)-b-poly (3-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)methylthiophene) (P3HT-b-P3TEGT), synthesized by a Grignard metathesis polymerization. The thin film of P3HT-b-P3TEGT was analyzed by grazing incidence X-ray scattering (GIXS), differential scanning calorimetry (DSC), spectroscopy and microscopy methods for the quantitative analysis. From these analyses, the block copolymer films form vertically oriented lamellar structure via phase separation and both domains consisted of molecular multi-layers in which the layers stack along a direction normal to substrate. The P3HT domains exhibited crystalline phase, which is originated from the ππ stacked thiophene backbones along in-plane direction. In contrast, the P3TEGT domains remained amorphous phase. Results obtained lead to conclusion that the amphiphilic diblock copolymer successfully demonstrated well-defined self-assembled structure in the thin films. |
| 저자 |
노예철1, Tomoya Higashihara2, Kaoru Ohshimizu2, 안병철1, 김경태1, 정성민1, 김영용1, 정정운1, 김미희1, 김진철1, 권원상1, 고용기1, 권경호1, Mitsuru Ueda2, 이문호1
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| 소속 |
1포항공과대, 2Tokyo Institute of Technology |
| 키워드 |
P3HT; GIXS; block copolymer
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| E-Mail |
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