화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 기능성 고분자
제목 Sulfonated poly(styrene-co-vinyl pyrrolidone)/PE composite membranes for polymer electrolyte fuel cells
초록 The sulfonated poly(styrene-co-vinyl pyrrolidone)/PE composite membranes were prepared using porous PE substrates for polymer electrolyte fuel cell (PEFC) applications. The porous PE film was filled with monomer solutions and then thermal polymerization was carried out to make composite membranes. The mixing ratio of two monomers, styrene and vinyl pyrrolidone, was varied and di-vinylbenzene(DVB) was used as a cross-linker. The prepared membranes were sulfonated using the chlorosulfonic acid and 1,2-dichloroethane mixture. The composite membranes were characterized in terms of their morphological, chemical and thermal properties. FT-IR spectra showed proper polymerization and sulfonation results. Scanning electron microscope(SEM) showed the dense surface and cross-sectional images of the composite membranes filled by sulfonated poly(styrene-co-vinyl pyrrolidone). The sulfonated composite membranes showed good proton conductivity and thermal stability.
저자 박승희1, 최영우1, 박진수1, 양태현1, 이영무2, 이원용1, 김창수1
소속 1한국에너지기술(연), 2한양대
키워드 polymer electrolyte; fue cell; composite membrane
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