| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
디스플레이_포스터 |
| 제목 |
Aggregation induced emission properties of triphenylamine-o-carborane dyads |
| 초록 |
We developed unique electron donor-π-acceptor dyad systems with diphenylamino at para- and meta-position of phenyl, and ortho-carborane. The para- and meta-substituted D- π -A systems showed three kinds of emission originated from the local excited state, a twisted intramolecular charge transfer state and an aggregation induced emission. The TICT emission showed strong solvent-polarity dependency, which is attributed to the dipole moment changes in excited TICT state. The strong AIE emission is observed in extremely nonpolar solvent such as n-hexane. Contrast to these, the steric hindrance between donors in para-substituted of D- π -A- π -D system prohibited the formation of TICT state, hence the LE and AIE emissions were observed dominantly. |
| 저자 |
김소연1, 조양진1, 손호진1, 조대원1, 한원식2, 강상욱1
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| 소속 |
1고려대, 2서울여자대 |
| 키워드 |
carborane; AIE; TICT
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| E-Mail |
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