화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1190
발표분야 고분자
제목 Fabrication of Nanocomposite Membranes Based on Graft Polymerization and Sol-gel Process for Polymer Electrolyte Membrane Fuel Cells
초록 Proton conducting nanocomposite membranes consisting of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(styrene sulfonic acid), i.e., P(VDF-co-CTFE)-g-PSSA graft copolymer and sulfonated silica and were prepared using a sol-gel reaction and subsequent oxidation of a silica precursor, i.e., (3-mercaptopropyl) trimethoxysilane (MPTMS). As a result, both proton conductivity (0.12 S/cm at 25 oC) and single cell performance (1.0 W/cm2 at 75 oC) were maximal at 5 wt% MPTMS.
저자 서진아, 김상진, 정예은, 지원석, 김종학
소속 연세대
키워드 graft copolymer; proton conducting membrane; nanocomposite; sol-gel
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