화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 고분자합성
제목 Synthesis of UV-induced self-crosslinkable polymers containing poly(ethylene glycol) and cardanyl moieties and their application to solid polymer electrolytes for lithium secondary batteries
초록 A series of copolymers comprising of poly(ethylene glycol) methyl ether methacrylate (PEGMA) and 2-hydroxy-3-cardanylpropyl methacrylate (HCPM) was synthesized via free radical copolymerization. The dimensionally-stable solid polymer electrolytes (SPEs) for lithium secondary batteries were prepared by blending the copolymers and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) followed by UV irradiation of 2 h. The prepared SPEs exhibited increased ionic conductivity as the content of HCPM monomeric unit decreased. The prepared SPEs have sufficient electrochemical stability and ionic conductivity for the application to all-solid-state lithium secondary batteries.
저자 백지훈, 김동균, 심지민, 이진홍, 최용석, 이종찬
소속 서울대
키워드 Radical Copolymerization; Solid Polymer Electrolytes; Lithium Batteries; Cardanol
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