학회 |
한국고분자학회 |
학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
권호 |
41권 1호 |
발표분야 |
고분자합성 |
제목 |
Synthesis of UV-induced self-crosslinkable polymers containing poly(ethylene glycol) and cardanyl moieties and their application to solid polymer electrolytes for lithium secondary batteries |
초록 |
A series of copolymers comprising of poly(ethylene glycol) methyl ether methacrylate (PEGMA) and 2-hydroxy-3-cardanylpropyl methacrylate (HCPM) was synthesized via free radical copolymerization. The dimensionally-stable solid polymer electrolytes (SPEs) for lithium secondary batteries were prepared by blending the copolymers and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) followed by UV irradiation of 2 h. The prepared SPEs exhibited increased ionic conductivity as the content of HCPM monomeric unit decreased. The prepared SPEs have sufficient electrochemical stability and ionic conductivity for the application to all-solid-state lithium secondary batteries. |
저자 |
백지훈, 김동균, 심지민, 이진홍, 최용석, 이종찬
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소속 |
서울대 |
키워드 |
Radical Copolymerization; Solid Polymer Electrolytes; Lithium Batteries; Cardanol
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E-Mail |
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