화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔)
권호 12권 1호, p.1081
발표분야 촉매 및 반응공학
제목 Study on Catalytic Activity over Ni/Mg/Al2O3 Hydrotalcite Derived Catalysts for Hydrogen Production
초록 Ni/Mg/Al2O3 catalysts derived from a hydrotalcite precursor were studied for steam reforming of LPG with temperature range of 600 ~ 850oC, feed molar ratio of H2O/C = 1.0 ~ 3.0, a space velocity of 10,000 ~ 30,000 h-1 and atmospheric pressure. Ni/Mg/Al2O3 catalyst was prepared by co-precipitation method and Ni/MgO and Ni/Al2O3 catalysts were produced by an incipient wetness method. The Ni/Mg/Al2O3 catalysts showed higher conversion and H2 selectivity under the tested conditions and the catalytic activity increased with increasing reaction temperature. The characteristics of the fresh and used catalysts was analyzed by N2 Physisorption, CO Chemisorption, XRD, SEM and TEM.
저자 김대현1, 강정식1, 이병권1, 윤영식2, 곽병성2, 홍석인3, 문동주1
소속 1한국과학기술(연), 2(주) SK, 3고려대
키워드 hydrotalcite; Ni catalsyt; Steam refroming
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