화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 UV-driven Switching of Chain Orientation and Liquid Crystal Alignment in Nanoscale Thin Films of a Novel Polyimide Bearing Stilbene Moieties.
초록 A novel photosensitive polyimide, poly(4,4’-stilbenylene 4,4’-oxidiphthalimide) (ODPA-Stilbene PSPI) was newly synthesized. The most surprising feature of this PSPI is that the PSPI films irradiated with linear polarized ultraviolet light (LPUVL) can favorably induce a unidirectional alignment of liquid crystals (LCs) in contact with the film surface and further switch the director of the unidirectionally aligned LCs from a perpendicular direction to a parallel direction with respect to the polarization direction of LPUVL by simply controlling the exposure dose in the irradiation process. These LPUVL-irradiated films were found to provide high anchoring energy to LCs, always giving very stable, homogeneous cells with unidirectionally aligned LCs regardless of the LC alignment directions.
저자 이택준1, 이문호1, 함석규1, 이승우2, 채복남1, 윤진환1, 김가희1, 허규용1, 진경식1, 진상우1, 박삼대1, 김동민1, 김진철1, 김경태1, 정정운1, 안병철1, 노예철1, 김승빈1
소속 1포항공대, 2영남대
키워드 LCD; alignment layer; photo-reactive
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