| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Robust Superhydrophobic Mats based on Electrospun Crystalline Nanofibers Combined with a Silane Precursor |
| 초록 |
We demonstrate the fabrication of solvent resistant, mechanically robust, superhydrophobic nanofibrous mats by electrospinning of poly(vinylidene fluoride) (PVDF) in the presence of inorganic silane materials. The solvent resistance and mechanical strength of nanofibrous mats were dramatically increased through the crystallization of as-spun PVDF fibers or incorporation of a tetraethyl orthosilicate (TEOS) sol into the nanofibrous matrix. The electrospun nanofibrous mats yielded a water contact angle of 156° that did not vary with TEOS content. The solvent resistance and mechanical robustness of the electrospun mats were significantly enhanced through extensive cross-linking of TEOS, even after short PVDF annealing times. The interpenetrating polymer network, which embeds polymer chains in a TEOS network, allows the fabrication of robust functional nanofibers by combining semicrystalline polymers with electrospinning techniques. |
| 저자 |
박송희1, 이송민1, 한중탁2, 이동렬1, 신화성3, 정영진1, 김주용1, 조정호1
|
| 소속 |
1숭실대, 2Korea Electrotechnology Research Institute, 3인하대 |
| 키워드 |
PVDF; electrospun; TEOS
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| E-Mail |
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