학회 |
한국공업화학회 |
학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
권호 |
20권 1호 |
발표분야 |
정밀화학_포스터 |
제목 |
Synthesis and Characterization of (E)- and (Z)-2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene Isomers |
초록 |
Horner-Wadsworth-Emmons reaction of bromobenzophenone and diethyl biphenyl-4-ylmethyl phosphonate generated 2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene as a mixture of (E)- and (Z)-geometric isomers. Each isomer could be isolated by recrystallization from ethyl acetate as a fine single crystal. The absolute structure of (E)-isomer was characterized by two dimensional NMR and single-crystal X-ray analyses. |
저자 |
이태원, 신주석, 이지영, 이하나, 박광용
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소속 |
중앙대 |
키워드 |
2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene; geometric isomer; crystal structure; triclinic
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E-Mail |
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