화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 정밀화학_포스터
제목 Synthesis and Characterization of (E)- and (Z)-2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene Isomers
초록 Horner-Wadsworth-Emmons reaction of bromobenzophenone and diethyl biphenyl-4-ylmethyl phosphonate generated 2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene as a mixture of (E)- and (Z)-geometric isomers. Each isomer could be isolated by recrystallization from ethyl acetate as a fine single crystal. The absolute structure of (E)-isomer was characterized by two dimensional NMR and single-crystal X-ray analyses.
저자 이태원, 신주석, 이지영, 이하나, 박광용
소속 중앙대
키워드 2-(Biphenyl-4-yl)-1-(4-bromophenyl)-1-phenylethene; geometric isomer; crystal structure; triclinic
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