| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Preparation of metal and metal oxide nanoparticles using poly(ethylene oxide) -b- poly(NiPAM)s |
| 초록 |
In this report we synthesized successfully water-soluble block copolymer exhibiting temperature-responsive behavior using poly(ethylene oxide)-based macroinitiator. n-Butyllithium-initiated ring-opening polymerization of ethylene oxide was performed in the mixture of benzene and DMSO at 40℃, followed by chain-end functionalization to obtain macroinitiator for atom transfer radical polymerization (ATRP). This PEO-based macroinitiator was converted into the RAFT (reversible addition fragmentation chain transfer) agent containing the dithioester group. Using the RAFT agent and AIBN as an initiator, RAFT polymerization of N-isopropylacrylamide (NiPAM) was successfully performed in toluene at 80℃ for 8h. The poly(ethylene oxide) -b- poly(NiPAM) was utilized for preparation of metal oxide nanoparticles such as ZnO or Fe3O4. We synthesized successfully and easily gold and silver nanoparticles stabilized by PEO -b- PNiPAM. |
| 저자 |
전희정1, 고다현1, 김경민1, 최송이1, 박형수2, 김정안1, 박건희1
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| 소속 |
1경희대, 2서강대 |
| 키워드 |
PEO; RAFT; NiPAM; Nanoparticles
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| E-Mail |
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