| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전)) |
| 권호 |
33권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis of poly(ethylene oxide) -b- polystyrene via anionic to radical transformation reation |
| 초록 |
Poly(ethylene oxide)-based macroinitiator for ATRP(atom transfer radical polymerization) was synthesized in a mixture of benzene, dimethylsulfoxide(DMSO), and tetrahydrofuran(THF) at 35℃, using potassium n-butyllithium and potassium tert-butoxide as an anionic initiating system under high vacuum via anionic polymerization of ethylene oxide. The PEO-based macroinitiator was converted to xanthate type of RAFT agnet in THF at 35℃ using potassium ethyl xanthogenate under nitrogen. PEO -b- PS was synthesized in toluene at 120℃ using PEO-based xanthate type RAFT agent and AIBN via RAFT radical polymerization of styrene. The block copolymers will be used in a variety of application fields such as nanotubes and thin film. In this presentation, we will report all the results for these experiments. |
| 저자 |
김근석1, 김정안1, 김태환1, 전희정1, 김진흥1, 황승상2, 백경열2, 홍순만2
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| 소속 |
1경희대, 2KIST |
| 키워드 |
RAFT polymerization |
| E-Mail |
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