| 학회 | 한국화학공학회 |
| 학술대회 | 2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔) |
| 권호 | 13권 1호, p.1250 |
| 발표분야 | 나노공정 심포지엄 |
| 제목 | Block Copolymers: Templates for New Functional Nanomaterials |
| 초록 | Block copolymers with well-defined nanoscopic structures have recently gained much attention for their potential uses as functional nanostructures. In this presentation, I first review the phase behaviors of block copolymers with various kinds of order-to-disorder transitions. Interestingly, block copolymers with lower disorder-to-order transition and closed-loop phase behavior exhibit the baroplastic property, enabling processing them at low temperatures with a modest pressure. Then, I discuss future applications of nanoporous templates based on block copolymer thin films, for instance, anti-reflective coating, the preparation of conducting polymer nanowires of poly(pyrrole), poly(3,4-ethylenedioxythiopene), and poly(3-hexyl thiopene) onto a glass coated with indium-tin-oxide, and the separation membranes for biomaterials. To obtain nanoporous templates, we used thin films of mixtures of polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) and PMMA homopolymer, followed by UV irradiation. These templates have cylindrical nanoholes spanning the entire thickness of the film, confirmed by grazing incidence X-ray scattering and 3-D transmission electron microscopy. |
| 저자 | 김진곤 |
| 소속 | POSTECH 화학공학과 |
| 키워드 | Self-Assembly; Block Copolymer; Nanomaterials |
| 원문파일 | 초록 보기 |
