| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Combined First-Principles and Experimental Study on Multi-components Olivine Cathode for Lithium Rechargeable Batteries |
| 초록 |
The electrochemical properties and phase stabilities of the multi-component olivine compound are studied experimentally and with first principles calculations. The formation of the solid solution from each single component olivine compounds is investigated by XRD study and the calculated first principles energy. We show that the solid solution of multi-components olivine is energetically favored at certain compositions. The electrochemical activity of the multi-components olivine is also investigated with conventional electrochemical characterization methods and first principles calculations. We also find that the delithiation mechanisms are significantly affected by a mixed transition metal distribution in the olivine framework. The evidence and its implication will be discussed in the talk. |
| 저자 |
강기석 |
| 소속 |
카이스트 |
| 키워드 |
리튬 이차 전지 |
| E-Mail |
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