화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 기능성 고분자
제목 Sulfonated poly(arylene ether sulfone) as template material for poly(3,4-ethylenedioxythiophene) dispersion
초록 Water soluble sulfonated poly(arylene ether sulfone) (SPES) was developed as template material for in-situ polymerization and dispersion of poly(3,4-ethylenedioxythiophene) (PEDOT). Sulfonated poly (arylene ether sulfone) was synthesized using 4,4′-hexafluoroisopropylidene diphenol (6FBPA) and 3,3′-disodiumsulfonyl-4,4′-dichlorodiphenylsulfone (SDCDPS) in N-methyl-2-pyrrolidone (NMP). PEDOT:SPES complex was developed by simple oxidative chemical polymerization of EDOT using sodium persulfate and iron sulfate in aqueous SPES solution. The PEDOT:SPES complex was spin coated over glass substrate and the dried PEDOT:SPES film was checked for their conductivity and transmittance. The conductivity increased ~200 fold after solvent treatment with transmittance of above 90%. After solvent treatment, the confirmation changes in the PEDOT structure were checked by AFM, Raman and UV spectroscopy.
저자 백현종, 홍영근, Subramani Devaraju
소속 부산대
키워드 PEDOT; conductivity; solvent treatment
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