| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 가을 (10/27 ~ 10/28, 고려대학교) |
| 권호 | 12권 2호, p.1842 |
| 발표분야 | 에너지/환경 |
| 제목 | Investigation of effects of Sn addition to the carbon-supported Pt electrocatalysts on the electrooxidation of primary alcohols |
| 초록 | Direct alcohol fuel cells (DAFCs), using renewable and environmentally friendly primary liquid fuels instead of fossil hydrocarbon, have been considered to be a potential development of fuel cells in terms of fuel usage and feed strategies [1]. In this study, We synthesized several carbon supported bimetallic PtSn electrocatalysts with different Pt:Sn atomic ratios (a metal loading of 20 wt. %) using borohydride reduction method with the freeze-drying procedures. The structure of catalysts was investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and the EXAFS, together with the electronic structure investigation of the Pt phase as the Sn content varied through XPS, XANES. The electro-catalytic activities of the catalysts were evaluated by cyclic voltammetry (CV) technique. Metal loadings on all catalysts were determined by inductively coupled plasma (ICP) analysis. References [1] B.C.H. Steele, A. Heinzel, Nature 414 (2001) 345 |
| 저자 | 김재홍1, 김원배2 |
| 소속 | 1광주과학기술원 신소재공학과, 2에너지전환나노재료연구실 |
| 키워드 | PtSn alloy; fuel cell; electrocatalyst; alcohol |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
