| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Synthesis and Photopolymerization of Acryl-Functionalized Siloxanes |
| 초록 |
The reactive precursors, mono-, di-acryl functionalized siloxanes, were synthesized. The acryl siloxane monomers were prepared from esterification reaction with allyl alcohol, and followed chemoselective hydosilylation with Pt catalyst. It was shown that the hydrosilylation proceeds two isomers, -CH2-CH(SiR2)-CH3 and -CH2-CH2-CH2-Si(R2). The photoinduced radical polymerzation of these monomers was studied and found to be all highly reactive. The formulates containing the synthesized monomers were tested surface morphology and mechanical properties for hard coating application. |
| 저자 |
조영길1, 이상영1, 임영돈1, 이순호1, 이성권2, 김승태2, 김환기1
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| 소속 |
1건국대, 2이피캠텍 |
| 키워드 |
Photopolymerization; hydosilylation; radical polymerzation
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| E-Mail |
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