학회 |
한국화학공학회 |
학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
권호 |
15권 1호, p.247 |
발표분야 |
분리기술 |
제목 |
Chromatographic Retention of Nine Solutes by the Use of Linear Solvation Energy Relationships in RP-HPLC |
초록 |
Linear solvation energy relationships (LSERs) are used to investigate the fundamental chemical interactions governing the retention of 9 compounds on a C18 column. The mobile phases studied involve three ionic liquids ([Bmim][BF4], [Hmim][BF4] and [Omim][BF4])with 25 to 75% methanol in water as mobile phase modifiers. The ability of the LSERs to account for the chemical interactions underlying solute retention is shown. A comparison of predicted and experimental retention factors suggests that LSER formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated. |
저자 |
전명래, 허효정, 주도, 노경호
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소속 |
인하대 |
키워드 |
Linear solvation energy relationships; chromatographic retention; ionic liquids; modifier
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E-Mail |
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원문파일 |
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