화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.247
발표분야 분리기술
제목 Chromatographic Retention of Nine Solutes by the Use of Linear Solvation Energy Relationships in RP-HPLC
초록 Linear solvation energy relationships (LSERs) are used to investigate the fundamental chemical interactions governing the retention of 9 compounds on a C18 column. The mobile phases studied involve three ionic liquids ([Bmim][BF4], [Hmim][BF4] and [Omim][BF4])with 25 to 75% methanol in water as mobile phase modifiers. The ability of the LSERs to account for the chemical interactions underlying solute retention is shown. A comparison of predicted and experimental retention factors suggests that LSER formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated.
저자 전명래, 허효정, 주도, 노경호
소속 인하대
키워드 Linear solvation energy relationships; chromatographic retention; ionic liquids; modifier
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