| 학회 |
한국화학공학회 |
| 학술대회 |
2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
| 권호 |
23권 2호, p.1924 |
| 발표분야 |
에너지 환경 |
| 제목 |
Benzyl headgroup-bearing cetyltrimethylammonium bromide (CTAB)-based micellar system for mediated electrolytic dechlorination in aqueous media |
| 초록 |
Electrocatalysis in micelles enables the difficult dehalogenation reactions of toxic organic pollutants to be achieved in aqueous media. A benzyl headgroup-bearing CTAB-based surfactant (cetylbenzyldimethylammonium chloride (CBDAC)) was studied for its structural effect on the dechlorination of allyl chloride (AC) by electrogenerated [Co(I)(bipyridine)3]+. First, the surfactant aggregates were characterized by CV and RDE techniques using [Co(II)(bpy)3]2+/[Co(I)(bpy)3]+ as redox probes. The information was subsequently used to explain the differences exerted by CBDAC and CTAB surfactants on the AC reduction process. |
| 저자 |
G. Muthuraman, K. Chandrasekara Pillai, 문일식
|
| 소속 |
순천대 |
| 키워드 |
친환경; 고효율
|
| E-Mail |
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| 원문파일 |
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