화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 에너지저장.변환_포스터
제목 Development of ultraviolet curable gel polymer electrolytes of PEO-PPO block copolymer blended with ionic liquid for supercapacitor
초록 GPEs blended with poly (ethylene oxide)-block-poly (propylene oxide) (PEO-PPO) copolymer and ionic liquid (IL) were successfully prepared through easy and simple polymerization via in-situ ultraviolet (UV) curing technology. UV-curable precursor (St-90R4) was synthesized through terminal group reaction of ethylenediamine tetrakis(ethoxylate-block-propoxylate) tetrol (Tetronic 90R4) with 4-vinylbenzyl chloride. The crosslinked GPEs were obtained by UV process of mixture containing St-90R4, styrene, divinyl benzene (DVB), IL, and photo-initiator. The ratio of styrene and DVB was adjusted to obtain optimized mechanical property of GPEs. The electrochemical properties of the supercapacitor using the prepared GPEs were evaluated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge-discharge test.
저자 김소희1, 이규태2, 김태호1, 홍영택1
소속 1한국화학(연), 2서울대
키워드 UV-curing; Gel Polymer Electrolyte; Supercapacitor
E-Mail