화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 기능성 고분자
제목 Fluorescence "turn-on" cysteine sensor based on reaction with aledhyde on polytriphenylamine derivative in the solid state
초록 Conjugated polymers (CPs) were used for electronic devices, such as light emitting diodes, photovoltaic cells and fluorescent sensor because they have a high signal amplification ability compared with that of corresponding monomer. However, CPs are only soluble in organic solvents, because they are commonly a hydrophobic in nature. This feature limited the application of CPs. As an alternative, water-soluble conjugated polymers (WSCPs) with charged groups have attracted much attention for electronic devices in aqueous solution. The detection of important biological thiols such as cysteine (Cys) is highly relevant to a variety of fundamental physiological processes in organisms. Herein, we synthesized novel anionic conjugated polymer containing triphenylamine. In addition, the selective reaction of the aldehyde group with N-terminal cysteines can form thiazolidines. As a result, emission shift of WSCP observed yellow to blue in the solid state.
저자 장근석, 김대근, 김종호, 이택승
소속 충남대
키워드 water-soluble conjugated polymer; cysteine sensor
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