화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1771
발표분야 에너지
제목 Highly active PdCo on carbon electrocatalyst for ethanol oxidation reaction
초록 Carbon-supported Pd and PdCo(1:2, 1:1, 2:1 and 3:1) catalysts are synthesized by chemical reduction with NaBH4. Their electrochemical properties are investigated by cyclic voltammetry, chronoamperometry and CO stripping voltammetry. In the cyclic voltammetry, the current density and onset potential of PdCo(1:1)/C are comparable to those of commercial catalysts and the current density increases according to the amount of Co. The onset potential of PdCo(1:1)/C in CO stripping test is negatively shifted by 40mV compared to that of Pd/C catalyst. Thus, PdCo(1:1)/C catalyst has possibility of replacing commercial Pt-based catalysts as an anode catalyst for DEFCs.

 
저자 한승훈1, 윤덕현2, 이재성2
소속 1POSTECH, 2UNIST
키워드 Fuel Cell; EOR; PdCo
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