화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터)
권호 14권 2호
발표분야 고분자
제목 A Water-Soluble Conjugated Polyacetylene by the Activated Polymerization of2-Ethynylpyridine
초록 Here, we synthesized a new self-dopable conjugated polymer by the activated polymerization of 2-ethynylpyridine with the ring-opening of 1,3-propanesultone without any additional initiator or catalyst. The photoluminescence spectrum of polymer showed that the PL peak is located at 552 nm corresponding to the photon energy of 2.29 eV. The cyclovoltammograms of polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. The oxidation current density of polymer versus the scan rates is approximately linear relationship in the range of 30 mV/sec 150 mV/sec.
저자 제갈영순1, 진성호2, 심상연3, 류원석4, 박종욱5, 임권택6
소속 1경일대, 2부산대, 3강릉원주대, 4영남대, 5가톨릭대, 6부경대
키워드 Water-soluble; conjugated polymer; synthesis; characterization; photoluminescence
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