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Physical organic chemistry of transition metal carbene complexes. 16. Reactions of (CO)(5)M=C(OR)Ph (M = Cr or W; R = Me or Et) with thiolate ions in aqueous acetonitrile. Complete kinetic dissection of the two-step mechanism Bernasconi CF, Kittredge KW, Flores FX Journal of the American Chemical Society, 121(28), 6630, 1999 |
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Physical organic chemistry of transition metal carbene complexes. 12. Spectroscopic detection and kinetic characterization of the intermediate in the nucleophilic substitution reaction of (CO)(5)Cr=C(OCH3)Ph with thiolate ions in aqueous acetonitrile Bernasconi CF, Flores FX, Kittredge KW Journal of the American Chemical Society, 120(31), 7983, 1998 |
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Physical Organic-Chemistry of Transition-Metal Carbene Complexes .7. Kinetics of Hydrolysis of (Co)(5)M=c(or)pH (M=cr, W, R=me, Et) and (Co)(5)Cr=(OMe)Ch=chph in Aqueous Acetonitrile Bernasconi CF, Flores FX, Kittredge KW Journal of the American Chemical Society, 119(9), 2103, 1997 |
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Physical Organic-Chemistry of Transition-Metal Carbene Complexes .5. Kinetics and Mechanism of Hydrolysis of (Co)(5)Cr=c(Och3)CH3 and (Co)(5)Cr=c(OCH2CH3)CH3 in Aqueous Acetonitrile Bernasconi CF, Flores FX, Sun WT Journal of the American Chemical Society, 117(17), 4875, 1995 |