| 1 |
Functionalized chiral vinyl aminosulfoxonium salts: Asymmetric synthesis and application to the synthesis of enantiopure unsaturated prolines, beta,gamma-dehydro amino acids, and cyclopentanoid keto aminosulfoxonium ylides
Tiwari SK, Gais HJ, Lindenmaier A, Babu GS, Raabe G, Reddy LR, Kohler F, Gunter M, Koep S, Iska VBR
Journal of the American Chemical Society, 128(22), 7360, 2006 |
| 2 |
Asymmetric modular synthesis of highly functionalized medium-sized carbocycles and lactones via ring-closing metathesis of sulfoximine-substituted trienes
Lejkowski M, Gais HJ, Banerjee P, Vermeeren C
Journal of the American Chemical Society, 128(48), 15378, 2006 |
| 3 |
Dynamic behavior of chiral sulfonimidoyl-substituted allyl and alkyl (dimethylamino)titanium(IV) complexes: Metallotropic shift, reversible beta-hydride elimination/reinsertion, and ab initio calculations of allyl and alkyl aminosulfoxonium ylides
Gais HJ, Bruns PR, Raabe G, Hainz R, Schleusner M, Runsink J, Babu GS
Journal of the American Chemical Society, 127(18), 6617, 2005 |
| 4 |
Fully stereocontrolled total syntheses of the prostacyclin analogues 16S-iloprost and 16S-3-oxa-iloprost by a common route, using alkenylcopper-azoalkene conjugate addition, asymmetric olefination, and allylic alkylation
Kramp GJ, Kim M, Gais HJ, Vermeeren C
Journal of the American Chemical Society, 127(50), 17910, 2005 |
| 5 |
Asymmetric synthesis of 2,3-dihydrofurans and of unsaturated bicyclic tetrahydrofurans through alpha-elimination and migratory cyclization of silyloxy alkenyl aminosulfoxonium salts. Generation and intramolecular O,Si-bond insertion of chiral disubstituted beta-silyloxy alkylidene carbenes
Gais HJ, Reddy LR, Babu GS, Raabe G
Journal of the American Chemical Society, 126(15), 4859, 2004 |
| 6 |
Palladium-catalyzed deracemization of allylic carbonates in water with formation of allylic alcohols: Hydrogen carbonate ion as nucleophile in the palladium-catalyzed allylic substitution and kinetic resolution
Lussem BJ, Gais HJ
Journal of the American Chemical Society, 125(20), 6066, 2003 |
| 7 |
Asymmetric synthesis of the highly potent anti-metastatic prostacyclin analogue cicaprost and its isomer isocicaprost
Lerm M, Gais HJ, Cheng KJ, Vermeeren C
Journal of the American Chemical Society, 125(32), 9653, 2003 |
| 8 |
Asymmetric synthesis of unsaturated, fused bicyclic proline analogues through amino alkylation of cyclic bis(allylsulfoximine)titanium complexes and migratory cyclization of delta-amino alkenyl aminosulfoxonium salts
Koep S, Gais HJ, Raabe G
Journal of the American Chemical Society, 125(43), 13243, 2003 |
| 9 |
A new strategy for the enantioselective synthesis of carba-prostacyclin analogues based on organocopper conjugate addition to a bicyclic azoene and its application to the synthesis of 13,14-dinor-inter-p-phenylene carbacyclin
van Bergen M, Gais HJ
Journal of the American Chemical Society, 124(16), 4321, 2002 |
| 10 |
Highly selective addition of chiral, sulfonimidoyl substituted bis(allyl)titanium complexes to N-sulfonyl alpha-imino esters: Asymmetric synthesis of gamma,delta-unsaturated alpha-amino acids bearing a chiral, electron-withdrawing nucleofuge at the delta-position
Schleusner M, Gais HJ, Koep S, Raabe G
Journal of the American Chemical Society, 124(26), 7789, 2002 |
