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Mechanism of the AppA(BLUF) Photocycle Probed by Site-Specific Incorporation of Fluorotyrosine Residues: Effect of the Y21 pK(a) on the Forward and Reverse Ground-State Reactions Gil AA, Haigney A, Laptenok SP, Brust R, Lukacs A, Iuliano JN, Jeng J, Melief EH, Zhao RK, Yoon E, Clark IP, Towrie M, Greetham GM, Ng A, Truglio JJ, French JB, Meech SR, Tonge PJ Journal of the American Chemical Society, 138(3), 926, 2016 |