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Unusual Isotope Effect in the Reaction of Chlorosilylene with Trimethylsilane-1-d. Absolute Rate Studies and Quantum Chemical and Rice-Ramsperger-Kassel Marcus-Calculations Provide Strong Evidence for the Involvement of an Intermediate Complex Becerra R, Boganov SE, Egorov MP, Krylova IV, Promyslov VM, Walsh R Journal of the American Chemical Society, 134(25), 10493, 2012 |
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Gas-Phase Kinetics of Chlorosilylene Reactions. I. ClSiH + Me3SiH: Absolute Rate Measurements and Theoretical Calculations for Prototype Si-H Insertion Reactions Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R Journal of Physical Chemistry A, 113(19), 5512, 2009 |
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The study of radical cations of Me3C-SiMe3 and Me3C-GeMe3 in alkane solutions using the method of time-resolved magnetic field effect and DFT calculations Borovkov VI, Potashov PA, Bagryansky VA, Molin YN, Faustov VI, Krylova IV, Egorov MP Chemical Physics Letters, 465(4-6), 307, 2008 |
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Surprisingly slow reaction of dimethylsilylene with dimethylgermane: Time-resolved kinetic studies and related quantum chemical calculations Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R Journal of Physical Chemistry A, 112(5), 849, 2008 |
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Direct time-resolved study of the gas-phase reactions of germylene with ethyl- and diethylgermane: Absolute rate constants, temperature dependences, and mechanism Becerra R, Boganov SE, Egorov MP, Krylova IV, Nefedov OM, Walsh R Journal of Physical Chemistry A, 111(8), 1434, 2007 |
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Direct detection of chlorosilylene and time resolved study of some of its reactions in the gas-phase using a new photochemical precursor Becerra R, Boganov SE, Egorov MP, Krylova IV, Nefedov OM, Walsh R Chemical Physics Letters, 413(1-3), 194, 2005 |
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Absolute rate constants for the reactions of germylene and dimethylgermylene with dimethylgermane: the deactivating effect of methyl groups in heavy carbenes Becerra R, Egorov MP, Krylova IV, Nefedov OM, Walsh R Chemical Physics Letters, 351(1-2), 47, 2002 |
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First gas-phase detection of dimethylstannylene and time-resolved study of some of its reactions Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Walsh R Journal of the American Chemical Society, 124(25), 7555, 2002 |