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A definitive example of a geometric "entatic state" effect: Electron-transfer kinetics for a copper(II/I) complex involving a quinquedentate macrocyclic trithiaether-bipyridine ligand Chaka G, Sonnenberg JL, Schlegel HB, Heeg MJ, Jaeger G, Nelson TJ, Ochrymowycz LA, Rorabacher DB Journal of the American Chemical Society, 129(16), 5217, 2007 |
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Effect of constrained donor atom orientations on the stabilities, complexation kinetics, redox potentials, and structures of macrocyclic polythiaether complexes. Copper(II) complexes with cyclopentanediyl derivatives of [14]aneS(4) in 80% methanol Kakos SH, Dressel LT, Bushendorf JD, Kotarba CP, Wijetunge P, Kulatilleke CP, McGillivary MP, Chaka G, Heeg MJ, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 45(2), 923, 2006 |
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Physical parameters and electron-transfer kinetics of the copper(II/I) complex with the macrocyclic sexadentate ligand [18]aneS(6) Chaka G, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 44(24), 9105, 2005 |
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Electron transfer by copper centers Rorabacher DB Chemical Reviews, 104(2), 651, 2004 |
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Electron-transfer kinetics of copper(II/I) tripodal ligand complexes Ambundo EA, Yu QY, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 42(17), 5267, 2003 |
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Electron-transfer kinetics of tris(2-(methylthioethyl))aminecopper(II/I). A tripodal ligand complex exhibiting virtual C-3v symmetry Ambundo EA, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 40(20), 5133, 2001 |
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Direct evidence for a geometrically constrained "entatic state" effect on copper(II/I) electron-transfer kinetics as manifested in metastable intermediates Yu QY, Salhi CA, Ambundo EA, Heeg MJ, Ochrymowycz LA, Rorabacher DB Journal of the American Chemical Society, 123(24), 5720, 2001 |
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Kinetics and mechanism of copper(II) complex formation with tripodal aminopolythiaether and aminopolypyridyl ligands in aqueous solution Ambundo EA, Deydier MV, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 39(6), 1171, 2000 |
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Effect of conformational constraints on gated electron-transfer kinetics. 3. Copper(II/I) complexes with cis- and trans-cyclopentanediyl-1,4,8,11-tetrathiacyclotetradecane Wijetunge P, Kulatilleke CP, Dressel LT, Heeg MJ, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 39(13), 2897, 2000 |
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Formation and dissociation kinetics and crystal structures of nickel(II)-macrocyclic tetrathiaether complexes in acetonitrile. Comparison to nickel(II)-macrocyclic tetramines Kulatilleke CP, Goldie SN, Heeg MJ, Ochrymowycz LA, Rorabacher DB Inorganic Chemistry, 39(7), 1444, 2000 |