Solubility and liquid-liquid equilibrium data are presented for ethanol-water-I-butanol, ethanol-water-1-pentanol and ethanol-water-1-hexanol ternary systems at room temperature (30 +/- 0.5)degreesC. From the above data binodal curves, tic lines and distribution curves have been determined with an aim to extract ethanol from the aqueous solution. Hand's method has been used to correlate tie lines and to calculate co-ordinates of plait points. The heterogeneous region of 1-hexanol at room temperature has appeared to be broader than those of I-pentanol and I-butanol systems. The solubility of ethanol in these systems increases with decreasing number of carbon atoms in the chain of solvents giving higher values of distribution coefficient and consequent by lowering the separation factor. The distribution coefficients are greater than I and the separation factors are considerably greater than 2 for all the solvents studied. All the solvents are found to be suitable for extraction of ethanol from the aqueous solution.