화학공학소재연구정보센터
Indian Journal of Chemical Technology, Vol.12, No.6, 689-694, 2005
Thermodynamic and ultrasonic studies of biomolecules in aqueous solutions of metal ion at 303.15K
Ultrasonic velocity, density and viscosity of tryptophan and glycine in aqueous solutions of ZnCl2 as well as CoCl2 have been measured at 303.15 K experimentally. From these experimentally measured values, the apparent molar volume (phi(v)), apparent molar compressibility (phi(K)), Viscosity coefficients of Jones-Dole equation and other parameters have been calculated at experimental temperature. These values have been used to explain molecular association, solute-solvent interactions through hydrogen bonding and solvation. The results have been discussed in the light of existing theories of molecular interactions and structural effects on solvent in solution.