This study presents a new geostatistical approach to characterization of the geometry and quality of a multilayer coal deposit using the data of seam thickness as a geometric property and the contents of ash, sodium, total sulphur, and the heating value as quality properties. A coal deposit in East Kalimantan (Borneo), Indonesia, which has a synclinal geological structure, was chosen as the study site. Semivariogram analysis clarified the strong dependence of heating value on ash content in the top and bottom parts of each seam and the existence of a strong correlation with sodium content over the sub-seams in the same location. The correlations between the geometry and quality of the seams were generally weak. A linear coregionalization model was used to derive the spatial correlation coefficients of two variables at each scale component from the single- and cross-semivariogram matrices. Because the data were correlated spatially in the same seam or over different seams, multivariate techniques (ordinary cokriging and factorial cokriging) were mainly used and the resultant spatial estimates were compared to those derived using a univariate technique (ordinary kriging). A factorial cokriging was effective to decompose the spatial correlation structures with different scales. Another important characteristic was that the sodium content shows distinct segregation: the low zones are concentrated near the boundary of the sedimentary basin, while the high zones are concentrated in the central part. The main component of sodium originates from the abundance of saline water. Therefore, it can be inferred that seawater had stronger effects on the coal depositional process in the central basin than in the border part. The geostatistical modeling results suggest that the thicknesses of all the major seams were controlled by the syncline structure, while the coal qualities chiefly were originated from the coal depositional and diagenetic processes. (c) 2007 Elsevier B.V. All rights reserved.