화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.47, No.3, 388-396, 2002
Vapor pressure and sublimation enthalpies of holmium trichloride, tribromide, and triiodide
The total vapor pressure of HoCl3, HoBr3, and HoI3 was measured by the torsion and Knudsen effusion methods. By a least-squares treatment of the obtained data, the following equations were selected as representative for the temperature dependence of their vapor pressures in the covered temperature ranges: HoCl3(s), log(p/kPa) 10.91 +/- 0.10 - (14216 +/- 150) (K/T) (from 883 to 994 K); HoCl3(1), log(p/ kPa) = 9.16 +/- 0.10 - (12466 +/- 150) (K/T) (from 1002 to 1164 K); HoBr3(s) log(p/kPa) 10.95 +/- 0.10 - (14168 +/- 150) (K/T) (from 904 to 1105 K), HoI3(s), log(p/kPa) = 12.24 +/- 0.10 - (14656 +/- 150) (K/T) (from 872 to 1066 K). When the data are treated by the second- and third-law methods, the standard sublimation enthalpies for HoCl3 and HoBr3, Delta(sub)Hdegrees(298 K) = 296 +/- 10 and 290 +/- 5 kJ.mol (1), respectively, were derived. For HoI3 the proposed enthalpy, Delta(sub)Hdegrees(298 K) = 296 +/- 8 kJ.mol(-1), was only derived by the second-law method. From this standard enthalpy, a set of free energy functions for solid HoI3 was evaluated by a third-law treatment of the data.