Total pressure measurements are reported for the binary mixtures of 2-ethoxyethanol with methyl acetate, ethyl acetate, propyl acetate, and ethyl propionate at 313.15 K and for 2-ethoxyethanol with methyl formate at 308.15 K. The data were obtained using a Van Ness type apparatus and were fitted to the modified Margules equation (or one of its simplified cases) using Barker's method. All mixtures show positive deviations from ideality and are represented by the model to within an average absolute deviation of approximately 0.06 kPa.