Densities and viscosities of binary mixtures of N,N-dimethylformamide (DMF) with benzyl alcohol and acetophenone have been measured at (298.15, 303.15, 308.15, and 313.15) K. Using the experimental data, excess molar volumes (V-E) and deviations in viscosity (Deltaeta) have been calculated. The excess molar volumes and deviations in viscosity have been fitted to the Redlich-Mster polynomial equation. McAllister's three-body interaction model has been used to correlate the kinematic viscosities of binary liquid mixtures with mole fractions.