Journal of Chemical and Engineering Data, Vol.49, No.2, 368-371, 2004
Henry's constants and infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in 2-propanol at 250-330 K
The Henry's constants and the infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in 2-propanol in the temperature range 250 K to 330 K are measured by a gas stripping method. The rigorous formula for evaluating the Henry's constants from the gas stripping measurements is used for these highly volatile mixtures. The accuracy of the measurements is about 2% for Henry's constants and 3% for the estimated infinite dilution activity coefficients. In the evaluations for the infinite dilution activity coefficients, the nonideality of the solute is not negligible, especially at higher temperatures, and the activity coefficients include the estimation uncertainty of about 1%.