Journal of Chemical and Engineering Data, Vol.50, No.1, 122-124, 2005
High-pressure phase equilibrium for ethylene plus ethanol at 283.65 K
The phase equilibria and saturated density for the ethylene + ethanol system at high pressures were measured at 283.65 K with a static-circulation apparatus. The experimental apparatus equipped with three Anton Paar DMA 512S vibrating-tube density meters was previously developed to measure vapor-liquid-liquid equilibria at high pressures. The coexisting phase composition and saturated density of each phase can be measured by means of the apparatus with a maximum temperature and pressure of 400 K and 20 MPa, respectively. The present experimental results include vapor-liquid, liquid-liquid, and vapor-liquid-liquid equilibria. The equilibrium composition and saturated density of each phase were determined by gas chromatography and vibrating-tube density meters, respectively. The experimental data were correlated with various equations of state.