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Journal of Applied Electrochemistry, Vol.26, No.5, 463-469, 1996
Chronoamperometry at Channel Electrodes - Analytical Theory of Transient-Behavior at Double Electrodes
An analytical theory is presented which permits the calculation of transient effects at widely-separated double channel electrodes. In particular the current response of a downstream (detector) electrode to a potential leap at an upstream (generator) electrode is established and theoretical predictions are found to be in excellent agreement with experiments carried out using the oxidation of N,N,N’,N’-tetramethyl-phenylenediamine in aqueous solution at a platinum double channel electrode.
Keywords:KINETICS