화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.52, No.2, 555-559, 2007
Binary diffusion coefficients of arachidonic acid ethyl esthers, cis-5,8,11,14,17-eicosapentaenoic acid ethyl esthers, and cis-4,7,10,13,16,19-docosahexanenoic acid ethyl esthers in supercritical carbon dioxide
The binary diffusion coefficients of arachidonic acid ethyl esthers (AA-EE), cis-5,8,11,14,17-eicosapentaenoic acid ethyl esters (EPA-EE), and cis-4,7,10,13,16,19-docosahexaenoic acid ethyl esthers (DHA-EE) in supercritical carbon dioxide were measured at temperatures from 308.15 K to 338.15 K and pressures from 8.42 MPa to 29.95 MPa by the Taylor-Aris capillary peak broadening method. The obtained diffusion coefficients are in the range of (5.54 x 10(-5)) cm(2).s(-1) to (13.8 x 10(-5)) cm(2).s(-1) with small differences between AA-EE, EPA-EE, and DHA-EE. The measured D-12 values were fitted with absolute average deviations of less than 2 % by three predictive models: Scheibel, Catchpole-King, and He-Yu-Su.