화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.53, No.3, 881-887, 2008
Density and viscosity experimental data of the ternary mixtures 1-propanol or 2-propanol + water+1-ethyl-3-methylimidazolium ethylsulfate. Correlation and prediction of physical properties of the ternary systems
In this paper, we have determined densities, rho, refractive indices, n(D), and dynamic viscosities, eta, of two ternary mixtures, 1-propanol + water + 1-ethyl-3-methylimidazolium ethylsufate (EMISE) and 2-propanol + water + EMISE, at 298.15 K over the whole composition range and at atmospheric pressure. Excess molar volumes, V-E, refractive index deviations, Delta n(D), viscosity deviations, Delta eta, and excess free energies of activation of viscous flow, Delta G*(E), have been calculated from experimental data and fitted to Cibulka and Singh et al. equations. The excess properties have been used to test several prediction models.